曝氧量对污水聚合物黏度影响的室内实验研究

随着我国东部老油田含水率逐年自然上升,产出污水既造成了环境破坏,又导致资源的浪费,因此,使用采出污水配制聚合物溶液进行回注的技术被各大油田广泛使用。而如今普遍使用的污水曝氧技术,虽然能够减小甚至消除污水中厌氧细菌对聚合物分解所造成的溶液黏度降低,但是过度的曝氧也会引起聚合物分子链发生断裂,从而减低溶液的黏度。采用室内实验,采用曝氧污水及厌氧污水配制聚合物溶液的方法,研究氧分子对于聚合物溶液黏度以及稳定性的影响。实验结果发现,使用曝氧污水所配制聚合物溶液的黏度要高于使用厌氧污水所配制聚合物溶液的黏度,在此基础上确定污水最佳曝氧浓度约为5 mg/L。     

Hygrothermal deformation of orthotropic nanoplates based on the state-space concept

This paper deals with the investigation of the effect of hygrothermal conditions on the bending of nanoplates using Levy type solution model employing the state-space concept. The nanoplates are assumed to be subjected to a hygrothermal environment. The two-unknown function plate theory is used to derive the governing differential equations on the basis of Eringen's nonlocal elasticity theory. The governing equations contain the small scale effect as well as hygrothermal and mechanical effects. These equations are converted into a set of first-order linear ordinary differential equations with constant coefficients. Analytical solution of bending response for nanoplates under combinations of simply supported, clamped and free boundary conditions is obtained. Comparison of the results with those being in the open literature is made. The influences played by small scale parameter, temperature rise, the degree of moisture concentration, boundary conditions, plate aspect ratio and side-to-thickness ratio are studied.     

The periodic system and the idea of a chemical element: From Mendeleev to superheavy elements

Like other scientific concepts, the idea of a chemical element has changed considerably over time, since it was first established in the Enlightenment era. In Dmitri Mendeleev's construction of the periodic system, he distinguished between simple substances and elements as defined by their atomic weights. The foundation of the periodic system on the latter concept led to several challenges. For example, the system seemed unable to accommodate the radioactive substances eventually recognised as isotopes. Around 1920, elements were consequently redefined in terms of their atomic numbers, a nuclear property that could be determined by X‐ray spectroscopy. Although this understanding of an element has stood the test of time, new questions turned up relating to the concept of an element following the syntheses of transuranic elements since the early 1940s. These syntheses of very heavy elements have additionally led chemists and physicists to reconsider the criteria for the discovery of a new element. Recently, elements have been officially recognised on the sole ground that a small number of very heavy atomic nuclei were identified. The paper discusses how the notion of an element was modified during different periods of time, the reasons for the modifications, and the values ascribed to them in the communities of chemists and physicists.     

A passivity‐based simple adaptive synergetic control for a class of nonlinear systems

For a class of nonlinear systems with the representation {A(x), B(x), C} and where the system parameters and dynamics are unknown, a simple adaptive synergetic controller ensuring the asymptotic convergence of the system to a desired manifold is proposed based on the technique of simple adaptive control (SAC). It is well known that the design of the synergetic control (SC) law requires a thorough knowledge of the system parameters and dynamics. Such problem obstructs the synthesis of the SC law and the designer is prompted to pass through the estimation methods, which, in turn, poses a problem of increasing the computation time of the control algorithm. To cope with this problem, a solution is proposed by modifying the original SC law to develop an SAC‐like adaptive SC law without the need of prior knowledge of the system. The stability of the proposed adaptive controller is formally proven via the Lyapunov approach. Experimental application to a quadrotor system is given to validate the theoretical results.     

Water chemistry,solution resistivity,and oxygen reduction reaction in simulated primary coolant of pressurized water reactors

The effect of temperature (25 °C–300 °C) on the ohmic potential drop (ΔE_Ω) and resistivity (R_sol) of a simulated primary coolant of the pressurized water reactors was investigated using electrochemical impedance spectroscopy (EIS) and galvanostatic potentiometry. The variations in the conductivity and pH of the solution showed that by increasing the temperature the magnitude of the R_sol and therefore ΔE_Ω of the system first decreases rapidly (until ~150 °C) and then reaches a relatively stable plateau value. Increasing the pressure of the system decreased the magnitude of the R_sol in the oxygenated coolant. Investigation of the oxygen reduction reaction (ORR) on platinum (Pt), 316L stainless steel (SS), Alloy 690, and carbon steel revealed the great effect of water chemistry, in particular pH on the rate of the ORR on these materials. OH^? adsorption on Pt reduced the rate of the ORR on this metal at temperatures higher than ~100 °C. Finally, it was found that higher H₃O⁺ concentrations reduce the rate of the ORR on iron‐ and nickel‐based alloys, while increasing the OH^? concentration at temperatures higher than ~150 °C accelerates the rate of the ORR on these alloys.     

高强WSTi544221合金组织与性能研究

研究了轧制变形量对WSTi544221合金棒材显微组织和力学性能的影响,并对Φ10 mm规格的棒材进行不同制度的固溶+时效处理,对比了不同热处理状态下棒材的组织和力学性能。结果表明,随着轧制变形量的增大,WSTi544221合金棒材的晶粒细化程度增大,强度逐渐提高,但塑性变化不大。经870℃×1 h/WC+520℃×6 h/AC固溶+时效处理后,强度与塑性可以获得良好匹配,当抗拉强度达到1 610 MPa、屈服强度达到1 531 MPa时,延伸率和断面收缩率可分别保持在12%和43%。     

Deep reinforcement learning-based cooperative interactions among heterogeneous vehicular networks

Most real-world vehicle nodes can be structured into an interconnected network of vehicles. Through structuring these services and vehicle device interactions into multiple types, such internet of vehicles becomes multidimensional heterogeneous overlay networks. The heterogeneousness of the overlays makes it difficult for the overlay networks to coordinate with each other to improve their performance. Therefore, it poses an interesting but critical challenge to the effective analysis of heterogeneous virtual vehicular networks. A variety of virtual vehicular networks can be easily deployed onto the native network by applying the concept of SDN (Software Defined Networking). These virtual networks reflect their heterogeneousness due to their different performance goals, and they compete for the same physical resources of the underlying network, so that a sub-optimal performance of the virtual networks may be achieved. Therefore, we propose a Deep Reinforcement Learning (DRL) approach to make the virtual networks cooperate with each other through the SDN controller. A cooperative solution based on the asymmetric Nash bargaining is proposed for co-existing virtual networks to improve their performance. Moreover, the Markov Chain model and DRL resolution are introduced to leverage the heterogeneous performance goals of virtual networks. The implementation of the approach is introduced, and simulation results confirm the performance improvement of the latency sensitive, loss-rate sensitive and throughput sensitive heterogeneous vehicular networks using our cooperative solution.     

积分中值屈服准则解析厚板轧制椭圆速度场

为解决非线性Mises比塑性功率积分困难以及由此导致的轧制功率解析式难以获得的问题,本文通过建立并利用线性比塑性功率表达式对提出的椭圆速度场进行能量分析,得到了轧制力能参数的解析解.文中通过对变角度屈服函数求积分中值,构建了一个新的屈服准则,它是主应力分量的线性组合,在π平面上的轨迹是逼近Mises圆的等边非等角的十二边形,其基于Lode参数表达式的理论结果也与实验数据吻合较好.同时,根据厚板轧制时金属流动速度从入口到出口逐渐增大的特点,提出了水平速度分量满足椭圆方程的速度场,该速度场满足运动许可条件.通过相应的轧制能量分析,获得了基于线性屈服准则的内部变形功率以及基于应变矢量内积法上的摩擦功率与剪切功率.在此之上,通过泛函的极值变分导出了轧制力矩、轧制力以及应力状态系数的解析解,并与现场实测数据进行了对比,结果表明利用本文提出的屈服准则与速度场所建立的轧制力矩与轧制力模型与实测值吻合较好,其中轧制力误差小于5.3%,轧制力矩误差在6%左右.